Volume 46, No 3, 2024, Pages 511-525
Evaluation of Corrosion Resistance of TiN and CrN Films Coated on SS304 Stainless Steel Using Cathodic Arc Deposition
Authors:
Vu Van Huy ,
Nikolai B. Rodionov ,
Valery A. Karpov ,
Ngo Thanh Binh ,
Doan Thanh Van ,
Nguyen Van Thanh
DOI: 10.24874/ti.1641.03.24.06
Received: 13 March 2024
Revised: 25 May 2024
Accepted: 22 June 2024
Published: 15 September 2024
Abstract:
Monolayer (TiN/Ti) and multilayer films (TiN/Ti; CrN/Ti, TiN/CrN/Ti) with an average thickness of 2300 nm were deposited on SS304 steel using the cathodic arc deposition method. Analysis revealed the presence of numerous macroparticles (peaks) and pinholes (valleys) uniformly distributed across the surface. The monolayer film exhibited superior surface quality compared to the multilayer films but demonstrated poor adhesion to the substrate. X-ray diffraction spectroscopy detected a noticeable shift in the preferred orientation of the deposited film, transitioning from (111) to (200) when employing a multilayer structure. Applying ceramic coatings onto stainless steel induced significant alterations in the potentiodynamic polarization curves of monolayer and multilayer films, resulting in a shift towards more noble potentials and lower corrosion currents than the substrate. Furthermore, the potential passive range expanded when employing multilayer structures based on TiN and CrN.
Keywords:
PVD, Corrosion behavior, CrN/TiN coating, Multilayer film, Biocompatibility